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Iterative solution of Eq (349) starts with the value Z = 1 substituted on the right side The calculated value of Z is returned to the right side and the process continues to convergence The final value of Z yields the volume root through V = Z R T I P

Equation (346) may be solved for the V in the numerator of the final fraction to give:

TABLE 12-1

When the user exits the Library application, the code will call the CleanUpProgram method to properly dispose of the connection object. Return to the General.vb module, and add that method.

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V = b + ( V + r b ) ( V + a b ) [ R T +a:;)-

This equation with a starting value of V = b on the right side converges upon iteration to a liquid or liquid-like root An equation for Z equivalent to Eq (352) is obtained when Eq (349) is solved for the Z in the numerator of the final fraction:

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6 For iteration a starting value of Z = , is substituted on the right side Once Z is known, the volume root is V = Z R T I P Equations of state which express Z as a function of T, and P, are said to be generalized, because of their general applicability to all gases and liquids Any equation of state can be put into this form to provide a generalized correlation for the properties of fluids This allows the estimation of property values from very limited information Equations of state, such as the van der Waals and RedlichIKwong equations, which express Z as functions of T, and P, only, yield two-parameter corresponding states correlations The SoaveRedlicWKwong (SRK) equation1' and the PengRobinson (PR) equation,12in which the acentric factor enters through function a(T,; w ) as an additional parameter, yield three-parameter corresponding-states correlations The numerical assignments for parameters r , a , Q, and \Ir, both for these equations and for the van der Waals and RedlicWKwong equations, are given in Table 31 Expressions are also given for a(T,; w ) for the SRK and PR equations

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Public Sub CleanUpProgram( ) ' ----- Prepare to exit the program. On Error Resume Next LibraryDB.Close( ) End Sub

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Given that the vapor pressure of n-butane at 350 K (7685%) is 94573 bar, find the molar volumes of (a) saturated-vapor and (b) saturated-liquid n-butane at these conditions as given by the RedlicWKwong equation

" G Soave, Chem Eng Sci, vol 27, pp 1197-1203, 1972 "D Y Peng and D B Robinson, Ind Eng Chem Fundam, vol 15, pp 59-64, 1976

To simplify things, we ll call this routine from the application s MyApplication_

For comparison, values of V uand V' calculated for the conditions of Ex 38 by all four of the cubic equations of state considered here are summarized as follows: ~"/crn~mol-~ Exp vdW RK SRK PR Exp ~~/cm~rnol-' vdW RK SRK PR

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The Soave/Redlich/Kwong and the PengIRobinson equations were developed specifically for vaporlliquid equilibrium calculations (Sec 142) Roots of equations of state are most easily found with a software package such as Mathcad@or ~ a ~ l ein which iteration is an integral part of the equation-solving routine @, Starting values or bounds may be required, and must be appropriate to the particular root of interest A Mathcad@program for solving Ex 38 is given in App D2

CleanUpProgram( )

Generalized correlations find widespread use Most popular are correlations of the kind developed by Pitzer and coworkers for the compressibility factor Z and for the second virial coefficient B l 3

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The correlation for Z takes the form:

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