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where Z O and Z' are functions of both Tr and P, When w = 0,as is the case for the simple fluids, the second term disappears, and Z O becomes identical with Z Thus a generalized correlation for Z as a function of T, and P, based on data for just argon, krypton, and xenon provides the relationship Z O = F'(T,, P,) By itself, this represents a two-parameter correspondingstates correlation for Z Since the second term of Eq (354) is a relatively small correction to this correlation, its omission does not introduce large errors, and a correlation for Z0 may be

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Now that the database connection is established, it s time to do something with it. The first four centralized routines implement much of the code we discussed earlier: the creation of data readers and tables, and the processing of general SQL code. Add them to the General module.

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used alone for quick but less accurate estimates of Z than are obtained from a three-parameter correlation Equation (354) is a simple linear relation between Z and o for given values of Tr and P, Experimental data for Z for nonsimple fluids plotted vs w at constant Tr and Pr do indeed yield approximately straight lines, and their slopes provide values for Z' from which the generalized function Z' = F'(T,, P,) can be constructed Of the Pitzer-type correlations available, the one developed by Lee and ~ e s l e r has '~ found greatest favor Although its development is based on a modified form of the Benedict/WebblRubin equation of state, it takes the form of tables which present values of Z0 and Z' as functions of Tr and Pr These are given in App E as Tables E1 through E4 Use of these tables often requires interpolation, which is treated at the beginning of App F The nature of the correlation is indicated by Fig 314, a plot of ZO vs Pr for six isotherms

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Figure 314 The LeeIKesler correlation for Z0 = FO(T,, Pr)

This snippet adds the following seven routines:

The LeeIKesler correlation provides reliable results for gases which are nonpolar or only slightly polar; for these, errors of no more than 2 or 3 percent are indicated When applied to highly polar gases or to gases that associate, larger errors can be expected The quantum gases (eg, hydrogen, helium, and neon) do not conform to the same corresponding-states behavior as do normal fluids Their treatment by the usual correlations is

Lee and M G Kesler,AIChEJ, vol 21, pp 510-527,1975

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Given a SQL statement, retrieve its results from the database, and put it all in a DataTable object. A SqlDataAdapter connects the SqlDataReader with the DataTable.

sometimes accommodated by use of temperature-dependenteffective critical parameters15For hydrogen, the quantum gas most commonly found in chemical processing, the recommended equations are: 436 Tc/K = (for HZ) (355) 218

vC/cm3mol-' =

(357)

Given a SQL statement, retrieve its results from the database, returning the associated SqlDataReader object.

2

where T is absolute temperature in kelvins Use of these effective critical parameters for hydrogen requires the further specification that w = 0

The tabular nature of the generalized compressibility-factor correlation is a disadvantage, but the complexity of the functions ZO and 2' precludes their accurate representation by simple equations However, we can give approximate analytical expression to these functions for a limited range of pressures The basis for this is Eq (337), the simplest form of the virial equation:

Roll back the transaction, undoing any changes that were part of the transaction. None of these routines include their own error-processing code; they either suppress errors with an On Error Resume Next statement, or rely on the calling routine to

Tell the difference between analog and digital camera operation Distinguish between slide and negative photography Pick ISO settings for a digital and film camera Match aperture and shutter speed settings for correct exposure Use the Sunny 16 Rule Modify the Sunny 16 Rule based on ISO and lighting conditions Adjust exposure manually Tweak exposure with your camera s EV settings Choose metering modes for better pictures Use exposure lock to optimize exposure Tell when to ignore the camera and make your own exposure decisions

Thus, Pitzer and coworkers proposed a second correlation, which yields values for B Pc/RTc:

Together, these two equations become:

|

Comparison of this equation with Eq (354) provides the following identifications:

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